査読付き原著論文

 

 

(1)    R. Wong, Y. Yokotoa, M. Wakisaka, J. Inukai, and Y.-S. Kim, “Deciphering the Redox-Dependent Electronic Interfacial Structure of Electroactive Self-Assembled Monolayers”, Journal of the American Chemical Society, accepted. DOI: 10.1021/jacs.8b05885. IF: 14.357

 

(2)    K. Hu, T. Ohto, L. Chen, J. Han, M. Wakisaka, Y. Nagata, J. Fujita, and Y. Ito, “Graphene Layer Encapsulation of Non Noble Metal Nanoparticles as Acid-Stable Hydrogen Evolution Catalysts”, ACS Energy Letters, 3(7), 1539-1544 (2018). IF: 12.277

 

(3)    Y. Ito, T. Ohto, D. Hojo, M. Wakisaka, Y. Nagata, C. Linghan, K. Hu, M. Izumi, J. Fujita, and T. Adschiri, “Cooperation between holey graphene and Ni Mo alloy for hydrogen evolution in an acidic electrolyte”, ACS Catalysis, 8(4), 3579-3586 (2018). IF: 10.614

 

(4)    K. Hu, S. Jeong, M. Wakisaka, J. Fujita, Y. Ito, “Bottom-up synthesis of porous NiMo alloy for hydrogen evolution reaction”, Metals, 8, 83 (2018). IF: 1.984 

 

(5)    S. Kobayashi, M. Aoki, M. Wakisaka, T. Kawamoto, R. Shirasaka, K. Suda, D. A. Tryk, J. Inukai, T. Kondo, and H. Uchida, “Atomically Flat Pt Skin and Striking Enrichment of Co in Underlying Alloy at Pt3Co(111) Single Crystal with Unprecedented Activity for the Oxygen Reduction Reaction”, ACS Omega, 3(1), 154-158 (2018).

 

(6)    S. Miyashita, M. Wakisaka, A. Iiyama, and H. Uchida, “Analysis of the Surface Oxidation Process on Pt Nanoparticles/Glassy Carbon Electrode by Angle-Resolved, Gracing Incidence X-ray Photoelectron Spectroscopy”, Langmuir, 33, 8877-8882 (2017). IF: 3.993 

 

(7)    S. Kobayashi, M. Wakisaka, D. A. Tryk, A. Iiyama, and H. Uchida, “Effect of Alloy Composition and Crystal Face of Pt Skin/Pt100-xCox [(111), (100) and (110)] Single Crystal Electrodes on the Oxygen Reduction Reaction Activity”, Journal of Physical Chemistry C, 121, 11234-11240 (2017). IF: 4.509 

 

(8)    Y. Ito, M. Izumi, D. Hojo, M. Wakisaka, T. Aida, and T. Adschiri, “One-step nanoporous structure formation using NiO nanoparticles: pore size control and pore size dependence of hydrogen evolution reaction”, Chemical letters, 46, 267-270 (2017). IF: 1.550

 

(9)    M. Wakisaka, S. Kobayashi, S. Morishima, Y. Hyuga, D. A. Tryk, M. Watanabe, A. Iiyama and H. Uchida, “Unprecedented Dependence of the Oxygen Reduction Activity on Co Content at Pt Skin/Pt–Co(111) Single Crystal Electrodes”, Electrochemistry Communications, 67, 47-50 (2016). IF: 4.847

 

(10) M. Wakisaka and M. Kunitake, “Direct electrochemical hydrogenation of toluene at Pt electrodes in a microemulsion electrolyte solution”, Electrochemistry Communications, 64, 5-8 (2016). IF: 4.847

 

(11) M. Chiwata, K. Kakinuma, M. Wakisaka, M. Uchida, S. Deki, M. Watanabe, and H. Uchida, “Oxygen Reduction Reaction Activity and Durability of Pt Catalysts Supported on Titanium Carbide”, Catalysis, 5, 966-980 (2015). IF: 2.000  

 

(12) J. Inukai, D. A. Tryk, T. Abe, M. Wakisaka, H. Uchida, and Masahiro Watanabe, “Direct STM Elucidation of the Effects of Atomic-Level Structure on Pt(111) Electrodes for Dissolved CO Oxidation”, Journal of the American Chemical Society, 145, 1476-1490 (2013). IF: 12.113 

 

(13) M. Wakisaka, T. Yoneyama, S. Ashizawa, Y. Hyuga, T. Ohkanda, H. Uchida, and M. Watanabe, “Structural variations of CO adlayers on a Pt(100) electrode in 0.1 M HClO4 solution: an in situ STM study”, Physical Chemistry Chemical Physics,15, 11038-11047 (2013). IF: 4.493 

 

(14) M. Watanabe, D. A. Tryk, M. Wakisaka, H. Yano, and H. Uchida, “Overview of recent developments in oxygen reduction electrocatalysis”, Electrochimica Acta, 84, 187-201 (2012). IF: 4.504 

 

(15) M. Wakisaka, S. Morishima, Y. Hyuga, H. Uchida, and M. Watanabe, “Electrochemical behavior of Pt-Co(111), (100) and (110) alloy single-crystal electrodes in 0.1 M HClO4 and 0.05 M H2SO4 solution as a function of Co content”, Electrochemistry Communications, 18, 55-57 (2012). IF: 4.847 

 

(16) M. Wakisaka, Y. Hyuga, K. Abe, H. Uchida, M. Watanabe, “Facile preparation and electrochemical behavior of Pt100-xCox(111) single-crystal electrodes in 0.1 M HClO4", Electrochemistry Communications, 13(4), 317-320 (2011). IF: 4.847 

 

(17) M. Wakisaka, Y. Udagawa, H. Suzuki, H. Uchida, and M. Watanabe, “Structural effects on the surface oxidation processes at Pt single-crystal electrodes studied by X-ray photoelectron spectroscopy”, Energy & Environmental Science, 4(5), 16662-1666 (2011). IF: 20.523 

 

(18) H. Uchida, H. Yano, M. Wakisaka, and M. Watanabe, “Electrocatalysis of the Oxygen Reduction Reaction at Pt and Pt-Alloys”, Electrochemistry, 79(5), 303-311 (2011). IF: 1.033 

 

(19) M. Wakisaka, S. Asizawa, H. Uchida, and M. Watanabe, "In Situ STM Observation of the CO Adlayer on a Pt(110) Electrode in 0.1 M HClO4 Solution", Langmuir, 26(12), 4184-4190 (2010). IF: 4.457 

 

(20) M. Wakisaka, S. Asizawa, H. Uchida, and M. Watanabe, “In situ STM observation of morphological changes of the Pt(111) electrode surface during potential cycling in 10 mM HF solution”, Physical Chemistry Chemical Physics, 12(16), 4184-4190 (2010). IF: 4.493 

 

(21) M. Wakisaka, H. Suzuki, S. Mitsui, H. Uchida, and M. Watanabe, “Identification and Quantification of Oxygen Species Adsorbed on Pt(111) Single-Crystal and Polycrystalline Pt Electrodes by Photoelectron Spectroscopy”, Langmuir, 25(4), 1897-1900 (2009). IF: 4.457 

 

(22) M. Wakisaka, H. Suzuki, S. Mitsui, H. Uchida, and M. Watanabe, “Increased Oxygen Coverage at Pt-Fe Alloy Cathode for the Enhanced Oxygen Reduction Reaction Studied by EC-XPS”, Journal of Physical Chemistry C, 112(7), 2750-2755 (2008). IF: 4.772 

 

(23) M. Wakisaka, S. Mitsui, Y. Hirose, K. Kawashima, H. Uchida, and M. Watanabe, “Electronic Structures of Pt-Co and Pt-Ru Alloys for CO-Tolerant Anode Catalysts in Polymer Electrolyte Fuel Cells Studied by EC-XPS”, Journal of Physical Chemistry B, 110, 23489-23496 (2006). IF: 3.302 

 

(24) M. Wakisaka, T. Ohkanda, T. Yoneyama, H. Uchida, and M. Watanabe, "Structures of a CO adlayer on a Pt(100) electrode in HClO4 solution studied by in situ STM", Chemical Communications, (21), 2710-2712 (2005). IF: 6.834 

 

(25) J. Inukai, M. Wakisaka, M. Yamagishi, and K. Itaya, "Adlayer of hydroquinone on Rh(111) in solution and in vacuum studied by STM and LEED", Journal of the Electrochemical Society, 152(2), E35-E39 (2005). IF: 3.266 

 

(26) J. Inukai, M. Wakisaka, and K. Itaya, "An STM study on the growth process of vapor-deposited hydroquinone adlayers on Rh(111) and Pt(111)", Chemical Physics Letters, 399(4-6), 373-377 (2004). IF: 1.897 

 

(27) C. Vericat, M. Wakisaka, R. Haasch, P. S. Bagus, and A. Wieckowski, "Binding energy of ruthenium submonolayers deposited on a Pt(111) electrode", Journal of Solid State Electrochemistry, 8(10), 794-803 (2004). IF: 2.446 

 

(28) J. Inukai, M. Wakisaka, M. Yamagishi, and K. Itaya, "Adlayer of hydroquinone on Pt(III) in solution and in a vacuum studied by STM and LEED", Langmuir, 20(18), 7507-7511 (2004). IF: 4.457 

 

(29) J. Inukai, M. Wakisaka, and K. Itaya, "p-xylene adlayers formed on Rh(111) and Pt(111) surfaces in vacuum", Japanese Journal of Applied Physics, 43(7B), 4549-4553 (2004). IF: 1.127 

 

(30) J. Inukai, M. Wakisaka, and K. Itaya, "Adlayer of naphthalene on Rh(111) studied by scanning tunneling microscopy", Japanese Journal of Applied Physics, 43(7B), 4554-4556 (2004). IF: 1.127 

 

(31) C.-K. Rhee, M. Wakisaka, Y. V. Tolmachev, C. M. Johnston, R. Haasch, K. Attenkofer, G.-Q. Lu, H. You, and A. Wieckowski, "Osmium nanoislands spontaneously deposited on a Pt(111) electrode: an XPS, STM and GIF-XAS study", Journal of Electroanalytical Chemistry, 554, 367-378 (2003). IF: 2.729 

 

(32) M. Wakisaka, M. Sugimasa, J. Inukai, and K. Itaya, "Structural change and electrochemical behavior of Pt(100)-hex-R0.7 degrees surfaces in gases and in solution", Journal of the Electrochemical Society, 150(2), E81-E88 (2003). IF: 3.266 

 

(33) S. Yoshimoto, R. Narita, M. Wakisaka, and K. Itaya, "The structure of a coronene adlayer formed in a benzene solution: studies by in situ STM and ex situ LEED", Journal of Electroanalytical Chemistry, 532(1-2), 331-335 (2002). IF: 2.729 

 

(34) M. Wakisaka, K. Suto, J. Inukai, and K. Itaya, "Structure of a p-xylene adlayer formed on a Rh(111) surface in vacuum studied by STM and LEED", Langmuir, 18(3), 729-733 (2002). IF: 4.457 

 

(35) T. Shimooka, S. Yoshomoto, M. Wakisaka, J. Inukai, and K. Itaya, "Highly ordered anthracene adlayers on Ag single-crystal surfaces in perchloric acid solution: In situ STM study", Langmuir, 17(20), 6380-6385 (2001). IF: 4.457 

 

(36) K. Suto, M. Wakisaka, M. Yamagishi, L. J. Wan, J. Inukai, and K. Itaya, "Highly ordered p-xylene adlayer formed on Rh(111) in HF solution: In situ STM and ex situ LEED", Langmuir, 16(24), 9368-9373 (2000). IF: 4.457 

 

(37) J. Inukai, Y. Osawa, M. Wakisaka, K. Sashikata, Y.-G. Kim, and K. Itaya, "Underpotential deposition of copper on iodine-modified Pt(111): In situ STM and ex situ LEED studies", Journal of Physical Chemistry B, 102(18), 3498-3505 (1998). IF: 3.302 

 

トランザクション

 

(1)    M. Wakisaka, S. Morishima, D. A. Tryk, H. Uchida, and M. Watanabe, “(Invited) Enhanced Activities for the Oxygen Reduction Reaction at Pt-Skin Layers on Pt-Co Alloy Single-Crystal Electrodes”, ECS Transactions, 64(3), 75-79 (2014).

 

(2)    M. Watanabe, M. Wakisaka, H. Yano, and H. Uchida, “Analyses of Oxygen Reduction at Pt-based Electrodes”, ECS Transactions, 16(2), 199-206 (2008).

 

書籍

 

(1)    M. Wakisaka, H. Uchida, and M. Watanabe, “Mechanism of the Enhanced Oxygen Reduction Reaction at Pt-Based Electrocatalysts: Identification and Quantification of Oxygen Species Adsorbed on Electrodes by X-Ray Photoelectron Spectroscopy” in Fuel Cell Catalysis and Biocatalysis: Theory and Fundamentals, Eds. A. Wieckowski, J. Norskov, and S. Gottesfeld, Chapter 4, 147-168, Wiley (2010). ISBN: 9780470410295.

 

特許

  

脇坂 暢, “有機ハイドライド製造装置及び有機ハイドライド製造方法”, 特願2014-174267.

 

解説・総説

  

(1)    脇坂 暢, 内田裕之, 渡辺政廣, “Pt系単結晶電極を用いた燃料電池反応解析”, 特集 構造規制機能界面のいま単結晶電極と自己組織化膜の進展―, Electrochemistry, 83(2), 96-100 (2015).

 

(2)    脇坂 暢, 内田裕之, 渡辺政廣, “電気化学-光電子分光法による燃料電池用Pt合金電極の解析”, 触媒, 53(1), 19-25 (2011).

 

(3)    内田 裕之,  宮武 健治, 野原 愼士, 矢野 啓, 脇坂 暢, B. Bae, 出来 成人, 渡辺 政廣, “固体高分子形燃料電池の高性能化のための要素材料研究開発の進展”, 科学と工業, 85(8), 321-327 (2011).

 

(4)    内田 裕之,  宮武 健治, 野原 愼士, 矢野 啓, 脇坂 暢, B. Bae, 渡辺 政廣, “固体高分子形燃料電池用電極触媒および高分子電解質膜の研究開発”, 溶融塩と高温化学, 53(3), 103-109 (2010).

 

招待・依頼講演

 

(1)    脇坂 暢, 依頼電気化学-光電子分光法を用いたPt基電極触媒の解析”, 2018年日本表面真空学会学術講演会, 201811(神戸国際会議場).

 

(2)    脇坂 暢, 依頼マイクロエマルションを反応場とした有機ハイドライド電解合成法”, 29回電解プロセス研究会, 2018920(大阪府立大学).

 

(3)    脇坂 暢, 國武雅司, 依頼マイクロエマルション中における芳香族炭化水素の電解水素付加反応”, 67回高分子討論会, 2018912(北海道大学).※北海道胆振東部地震により要旨のみ発表

 

(4)    脇坂 暢, 招待マイクロエマルションを反応場とした芳香族炭化水素の電解水素化”, 68回コロイドおよび界面化学討論会, 201796(神戸大学)

 

(5)    脇坂 暢, 田本加代子, 國武雅司, 依頼マイクロエマルションを用いた有機ハイドライド直接電解合成法”, 66回高分子討論会, 2017920(愛媛大学)

 

(6)    脇坂 暢, “電気化学-光電子分光法によるPt電極触媒上の吸着種のキャラクタリゼーション”, 21回キャラクタリゼーション講習会, 20111014(名古屋).

 

(7)    脇坂 暢, “光電子分光法並びに走査型トンネル顕微鏡を用いたPt(111)単結晶電極の表面酸化還元過程の解析”, 9 回燃料電池基盤技術研究懇話会, 201010(富士吉田)

 

(8)    脇坂 暢, 犬飼潤治, 内田裕之, 渡辺政廣, “1B07電気化学-光電子分光法並びに電気化学-走査型トンネル顕微鏡によるPt単結晶電極の表面酸化過程の解析”, 2010年電気化学秋季大会, 201092(神奈川工科大学).

 

(9)    脇坂 暢, 犬飼潤治, 内田裕之, 渡辺政廣, “電気化学-光電子分光法並びに電気化学-走査型トンネル顕微鏡を用いた燃料電池反応解析”, 2009年度実用表面分析会, 20091119(山梨大学).

 

(10) 脇坂 暢, “電気化学-光電子分光法を用いた燃料電池用Pt系電極触媒の解析”, 日本材料学会第159X線材料強度部門委員会, 2009102(山梨大学).

 

(11) 脇坂 暢, 内田裕之, 渡辺政廣, “依頼講演(4F19)電気化学-光電子分光法を用いたPt系電極における酸素還元反応の解析”, 104回触媒討論会, 2009930(宮崎大学).

 

(12) 脇坂 暢, “XPSおよびSTMを用いた燃料電池電極触媒の研究”, 触媒学会山梨地区講演会, 2007314(山梨大学).

 

学会発表(2015~)

 

(1)    脇坂 暢, 井上光浩, 阿部孝之, “マイクロエマルションを反応場としたPt-Ru電極触媒上におけるトルエンの電解水素付加反応”, 2018年電気化学会秋季大会, 2018926(金沢大学).

 

(2)    M. Wakisaka, “(Poster) Reaction Mechanism of Electrochemical Hydrogenation of Toluene at Pt Electrodes in Toluene/H2SO4 Microemulsion System”, 69th annual meeting of ISE, Sep. 5, 2018 (Bologna, Italy).

 

(3)    川本鉄平, 小林 駿, 白坂 亮, 青木 誠, 須田耕平, 脇坂 暢, 近藤敏啓, 秋山朋弘, 渡辺 剛, 廣沢一郎, 犬飼潤治, 内田裕之, “表面X線散乱測定を用いた白金コバルト合金単結晶電極表面構造解析”, Spring-8シンポジウム2018, 2018825-26(姫路市市民会館).

 

(4)    S. Kobayashi, M. Aoki, M. Wakisaka, T. Kawamoto, R. Shirasaka, K. Suda, D. A. Tryk, J. Inukai, T. Kondo, and H. Uchida, “ANALYSES OF SURFACE STRUCTURE AND LAYER-BY LAYER COMPOSITIONS OF Pt-SKIN/Pt3Co(111) SINGLE CRYSTAL ELECTRODE WITH HIGH ACTIVITY FOR THE OXYGEN REDUCTION REACTION”, 8th International Fuel Cell Workshop 2018, Aug. 23-24, 2018 (Kofu, Japan).

 

(5)    S. Kobayashi, M. Aoki, M. Wakisaka, T. Kawamoto, R. Shirasaka, K. Suda, J. Inukai, T. Kondo, H. Uchida, “Multilateral Analyses of Pt-skin/Pt3Co(111) Single Crystal Electrode with Extremely High Activity for the Oxygen Reduction Reaction”, 22nd Topical Meeting of ISE, Apr. 16, 2018 (Tokyo, Japan).

 

(6)    脇坂 暢, “Pt電極上における芳香族有機分子の電解水素付加反応”, 電気化学会第85回大会, 201839(東京理科大).

 

(7)    脇坂 暢, “マイクロエマルションを反応場としたトルエンの電解水素化”, 2017年電気化学会北陸支部秋季大会, 2017112(金沢大学).

 

(8)    須田耕平, 青木 誠, 小林 駿, 川本鉄平, 脇坂 暢, 近藤敏啓, 秋山朋弘, 渡辺 剛, 廣沢一郎, 犬飼潤治, 飯山明裕, 内田裕之, “燃料電池用高活性ナノ粒子触媒モデルとしての白金コバルト合金単結晶電極”, 14Spring-8産業利用報告会, 201791(川崎市産業振興会館)

 

(9)    脇坂 暢, 田本加代子, “マイクロエマルションを用いた白金黒電極上におけるベンゼン,トルエンおよびキシレンの電解水素化”, 電気化学会第84回大会, 2017325(首都大東京).

 

(10) 青木 誠, 小林 駿, 脇坂 暢, 近藤敏啓, 犬飼潤治, 飯山明裕, 内田裕之, “水素加熱処理したPt-Co(111)合金単結晶電極における酸素還元活性の組成依存性と表面構造”, 57回電池討論会, 20161130(幕張).

 

(11) M. Wakisaka and M. Kunitake, “(Poster) Structural Effects on Reaction Rate and Selectivity for Direct Electrochemical Hydrogenation of Aromatic Hydrocarbons at Pt Electrocatalysts”, PRiME 2016, Oct 4, 2016 (Honolulu, Hawaii).

 

(12) S. Miyashita, M. Wakisaka, A. Iiyama and H. Uchida, “(Poster) EC-XPS Analysis of Oxygen Species Adsorbed on Pt-Nanoparticle Model Electrodes“, PRiME 2016, Oct 5, 2016 (Honolulu, Hawaii).

 

(13) S. Kobayashi, M. Wakisaka, D. A. Tryk, A. Iiyama, and H. Uchida, “(Poster) Effect of HClO4 Concentration on Oxygen Reduction Reaction Activity at Pt and Pt-Co Alloy Single Crystal Electrodes”, PRiME 2016, Oct 5, 2016 (Honolulu, Hawaii).

 

(14) M. Wakisaka, S. Kobayashi, M. Aoki, T. Kondo, J. Inukai, and H. Uchida, “(Poster) Pt-Co(111) Single-Crystal Electrodes Prepared under H2 Atmosphere: Alloying, Surface Structure, and Oxygen Reduction Reaction Activity”, ECAT2016, Sep. 14, 2016 (Shonan, Japan).

 

(15) 脇坂 暢, 國武雅司, “マイクロエマルションを反応場とした新規有機ハイドライド電解合成”, 化学工学会第48回秋季大会, 201696(徳島大学).

 

(16) 脇坂 暢, 國武雅司, “マイクロエマルションを用いたトルエンの電解水素化反応”, 電気化学会第83回大会, 2016331(大阪大学).

 

(17) 宮下翔太, 脇坂 暢, 渡辺政廣, 飯山明裕, 内田裕之, “EC-XPS によるPt ナノ粒子モデル電極上の吸着酸素種の解析”, 56回電池討論会, 20161111(名古屋).

 

(18) M. Wakisaka and M. Kunitake, “Direct Electrochemical Hydrogenation of Aromatic Molecules at Pt Electrode in Microemulsion Electrolyte Solution”, 66th annual meeting of the ISE, Oct 7, 2015 (Taipei, Taiwan).

 

(19) 小林 駿, 森嶋翔也, 脇坂 , Donald A. Tryk, 渡辺政廣, 内田裕之, “Pt-Co(111)(110)及び(100)単結晶回転ディスク電極における酸素還元活性の合金組成依存性”, 電気化学会第82回大会, 2015315(横浜国立大学).